![]() ![]() Where the bonding cannot be expressed by a single Lewis formula. What is resonance? Is it a physical process? No way! It is just a concept, a word, used to describeĭelocalized electrons within certain molecules or polyatomic ions ![]() The concept of a chemical bonding was already so tremendously useful in chemistry that the choice was actually predetermined, and in 1928 Linus Pauling introduced the concept of resonance between several valence-bond structures of a molecule. At that point chemists had two choices: either abandon the valence bond theory or introduce another theoretical concept into it, introduce a new word in our language making it possible to communicate with nature in this language. Nature refused to "speak" with us in the language of chemical bonding. Indeed, all carbon-carbon bond lengths are equal in benzene, but the valence bond theory were not able to account for that simple fact. That is what actually happened with the valence bond theory as it was originally formulated. This is a very dangerous road, because, after all, who are we to tell nature which language to speak? Nature will likely refuse to "speak" with us in that language, and that would be it. However, it is often so tempting to force it to speak with us in a different language, in a language of our theoretical concepts (such as, for instance, the concept of a chemical bonding), no matter how fuzzy they are. Scientific theories basically tell us how nature could be described, and they do so in the language of mathematics, since it is the only language nature can unambiguously "speak" with us. It is practically helpful in description of a reality, but no one will say that it is actually a part of it.ĭo not be afraid of all this business, because it is the way science generally works. It is a concept, purely theoretical construction. It is just something something which is formed whenever orbitals overlap. Read the above quote carefully one more time: it is not even a definition! What we just say is that whenever half filled valence atomic orbitals of two atoms overlap a covalent bond is formed, but we do not say what exactly is a covalent bond. Note that atomic orbitals also do not exist in the same sense as electrons and nuclei do, but an orbital has at least some strict mathematical and physical meaning, while a chemical bond, as introduced above, does not. So, this is the way the concept of chemical bonding enters the scene in the valence bond theory: a chemical bond is used to describe overlapped atomic orbitals of two atoms in a molecule. In other words, chemical bonds do not exist in the same sense as electrons and nuclei do.įor instance, the concept of resonance was introduced by Linus Pauling in the framework of the so-called valence bond theory, according to whichĪ covalent bond is formed between the two atoms by the overlap of halfįilled valence atomic orbitals of each atom containing one unpaired In reality we do have electrons and nuclei that constitutes a molecule, but a chemical bond is merely a theoretical concept introduced in the framework of a scientific theory. Now please, take a deep breathe and repeat with me: there are no bonds. We know that in reality benzene has no pure single or double bond. However, I decided to somewhat clarify the matter emphasising few important points. As I mentioned in my comment, the Wikipedia article on resonance provides a rather nice description of the subject where the Resonance in quantum mechanics section is of particular interest for the question asked. ![]()
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![]() ![]() To deactivate an app, right click its icon in the dock and select Quit option (or choose VMware Fusion > Quit VMware Fusion on the Menu bar).Īlso, you can access the Activity Monitor (located in /Applications/Utilities/ folder), and see if there is any background process pertaining to the app. Prior to the removal of VMware Fusion, you should first log into your Mac with an administrator account, and turn VMware Fusion off if it is running. In this post we will discuss the following questions: (1) What is the correct way to uninstall VMware Fusion ? (2) How to ensure all its accompanying components are removed safely? And (3) is there a shortcut for both Mac novices and experts to take to accomplish VMware Fusion removal effortlessly? Conventional Steps to Uninstall VMware Fusion for Mac Even for the experienced users, they may also get lost when trying to uninstall a problematic, stubborn or even malicious application. In the latter case it is quite necessary to clean out those junk files from your Mac for complete removal.įor some novice users, they may have no idea how to remove VMware Fusion in a proper way. These vestiges can be very small in size, thus leaving them alone may not affect your Mac performance, yet they can also be a large chunks of useless files that occupy a large portion of your hard drive space. However, a fact is often neglected that, even the stand-alone software may might still leave its configuration and preferences files on multiple system directories after you carry out a basic uninstall. Generally speaking, most Mac applications are separate bundles that contain the executable and any associated resources for the app, and therefore users can easily remove any unwanted software (if they are installed properly) from their Macs. In normal cases Mac users just need to simply drag and drop the target app to the Trash and then empty the Trash to perform the standard uninstallation. Uninstalling applications in macOS/Mac OS X is quite different from that in Windows operating system. Things you should know about Mac app removal: How to uninstall VMware Fusion on Mac computer? If you encounter problem when trying to delete VMware Fusion as well as its associated components, read through this removal tutorial and learn about how to perfectly remove any unwanted applications on your Mac. ![]() ![]() You can see a folder called ‘tool’ with the latest VMware tools.VMware Fusion Removal Tutorial - How to Easily Uninstall VMware Fusion ![]() Execute win-update-tools.cmd from the unlocker extracted location. The VMware unlocker tool has a script to download the latest Darwin VMware tools for macOS. Where can I download the latest VMware tools for macOS on Windows OS? Then we can use the pre-installed macOS VMware images or modified ISO files to get Mac OS on VMware. We need to download and run a VMware unlocker to enable the support for macOS on Windows. VMware workstations or players for Windows do not support Mac OS officially. How to get Mac OS on VMware – Windows OS? This step will patch the VMware workstation on your Linux computer and support macOS as a guest virtual machine. Execute the lnx-install.sh file from the terminal with the root access. The same Unlocker tool has the installation script for Linux OS. With these all information, you must have a clear idea of downloading and installing the VMware macOS unlocker on Windows 11/10 and older versions. ![]() ![]() ![]() No, crawfish cannot cause colic in breastfed babies. Can crawfish cause colic in breastfed babies? However, eating a balanced diet and consuming adequate amounts of fluids can help to increase milk supply for breastfeeding mothers.Īdditionally, some studies have found that taking certain dietary supplements, such as fenugreek, can help to increase milk production. There is no scientific evidence to suggest that eating crawfish has any effect on milk production. No, crawfish does not increase milk supply. Therefore, it is recommended that mothers introduce crawfish gradually and in small amounts to monitor any potential reactions. Therefore, it is recommended that mothers who are breastfeeding avoid consuming these foods in order to reduce the risk of gas in their babies.Īdditionally, it is important to note that the digestive systems of breastfed babies are still developing and prone to sensitivity. However, it is important to note that certain foods, such as garlic and onions, can pass through breast milk and cause gas in babies. Does crawfish cause gas in breastfed babies?īased on current research, there is no evidence to suggest that crawfish causes gas in breastfed babies. Overall, eating crawfish while breastfeeding is generally considered safe, but it is important to be aware of the potential risks and monitor for any reactions. However, it is important to be aware of some potential risks.Ĭrawfish can be high in mercury, which can be passed to the baby through the mother’s milk.Īdditionally, crawfish can cause allergic reactions in some people, so it is important to be aware of any food allergies and be sure to monitor the baby for any reaction after consuming crawfish.Īdditionally, if the crawfish is cooked with any spices or seasonings, the baby may be sensitive to them as well so it is important to be aware of what seasonings were added. It is generally considered safe to eat crawfish while breastfeeding. By the end of this article, you’ll have a better understanding of the health benefits and safety considerations of eating crawfish while breastfeeding. We’ll also look at how to ensure that you and your baby are safe while consuming crawfish. ![]() This article will explore the potential benefits of eating crawfish while breastfeeding, as well as any potential safety concerns. While some may be concerned about the health and safety of consuming crawfish while breastfeeding, the truth is that it is safe. Crawfish is a popular seafood delicacy enjoyed by many people. ![]() ![]() In some areas, you can even get gigabit speeds for prices similar to what you're already paying. The newest wireless technologies IEEE 802.11ac (Wi-Fi 5) and 802.11ax (Wi-Fi 6 and Wi-Fi 6E) offer superior download and upload speeds as well as improved range compared to older Wi-Fi technologies, such as IEEE 802.11b, g, and others. If your speeds aren't up to snuff but do reflect the plan you're paying for, then it may be time to upgrade to a faster option. If you aren't getting the speeds your plan should be delivering, you may need to complain to your ISP. Youd set a router up somewhere near the center of your house and. With a WiFi repeater you can effectively double the coverage area of your WiFi network - reaching far. The Best Wi-Fi Extenders for Fast Home Internet Eliminate your network’s dead zones with the help of one of these boosters. Just a few short years ago, getting good WiFi into your home was a hit and miss kind of deal. It works by receiving your existing WiFi signal, amplifying it and then transmitting the boosted signal. A WiFi repeater or extender is used to extend the coverage area of your WiFi network. If your best efforts at setting up a newer router still don't give you the streaming speeds you expect, the problem may lie farther up the line with your service provider.Ĭheck your speeds using a free service like or . A WiFi repeater could be the solution for you. Get faster Wi-Fi: Call your service providerĪt the end of the day, your router setup is just one part of the networking puzzle. This not only avoids the amorphous problems of signal strength, potential interference and various wireless standards, it also frees up your Wi-Fi for all of the other stuff you like to do online, like send snarky Facebook messages to your friends about the latest Netflix show.Īnd you may still be able to do this for TVs in distant rooms, if you have a mesh router extension with an Ethernet port. If your TV is located anywhere near your router, a better option may be to connect directly with an Ethernet cable. ![]() Is Ethernet faster than Wi-Fi?įinally, for the best network connection and optimal streaming performance, Wi-Fi may not be the best choice. ![]() Wi-Fi extenders tend to be much less expensive, but mesh routers offer better speeds, simpler day-to-day use and nicer looking designs. You can use something from our list of the best Wi-Fi extenders (also called a signal booster, or Wi-Fi repeater) to add a little bit more coverage area – perfect for getting better signal in that one room that never gets strong Wi-Fi – or you can upgrade to one of the best mesh Wi-Fi systems, which maintains excellent speeds over a much larger area.īoth of these options use extra devices in addition to your router to spread wireless signal far and wide throughout your home. In these instances, you'll want to stretch your wireless coverage area, and you have two ways to do it. ![]() ![]() ![]() Choose a slow-release, balanced fertilizer like the one we carry. Fertilizingįertilize in early spring and when planting to give your tree a boost. Either condition can harm a Japanese Maple. Do not allow the the soil to dry completely or be overly saturated. Japanese Maples should be watered often enough to keep the soil moist. Do not allow the mulch to touch the trunk as this increases the chances of pests and disease. Mulching will keep the roots moist and protect them from extreme temperatures in winter. However, Japanese Maples will adapt to a variety of soils. Japanese Maples prefer soil that is well-drained, but moist, neutral to slightly acidic, and nutrient rich. ![]() PlantingĮmperor Maples tolerate full sun to part shade. However, if you avoid freezing and hot temperatures you can plant your Maple almost any time of the year. Spring and Fall are ideal times to plant. ![]() When planting your Emperor One Maple be sure you have the right location and conditions for your new tree to thrive. These hardy Japanese maples sell out fast! Order yours today! These Japanese Maples can grow in zones 5-9. The Emperor One is heat tolerant and rarely encounters issues with sun scorch even in full sun.Įmperor Japanese Maples thrive in partial shade to full sun and adapt to various, moist soils. Emerging from dormancy a couple of weeks later actually gives this Japanese maple a jump start over other varieties. This variety boasts excellent color retention under a variety of conditions.Įmperor Maples are ideal for cooler regions where delicate, new leaves are often killed or damaged by late spring frost. Cool temperatures enliven the leaves of the Emperor One Japanese Maple transforming them into a vibrant, fiery red. The attractive leaves are a deep shade of burgundy-plum in the spring and summer. This extraordinarily stunning tree adds interest, distinction, and property value to your home! This dwarf shade tree, also known as the Red Emperor, offers 3 seasons of rich red to purple color. Emperor One is an improved variety of upright Japanese Maple that is similar to the classic Bloodgood. ![]() ![]() All you need to begin your sheep farm is two sheep and the necessary wheat to breed them. ![]() So how can you get enough wool to make all of these banners? Simple, a sheep farm. When making all of these beautiful Pride banners, you will require a ton of wool, which can sometimes be difficult to find, especially if you live in a biome that does not often have many sheep. If you want to mix two dyes to create a third color, put two next to each other horizontally on the grid. Put the ingredient on the crafting grid to create a dye. See how many colour combinations you can do. Double Band Fishtail Once you have mastered the Fishtail design try this one. Have a play with the Fishtail design in the colours of the rainbow. Fishtail Another easy design for beginners. You create dyes by crafting them from plants such as flowers, crushing skeleton bones (bone meal creates white dye) or ink sacs (black dye), mixing dyes of different colors, smelting plants (fx a sea pickle to get green dye) or trading with a Wandering trader. Single This is one of the easiest designs to get you started on your Rainbow Loom. You might also enjoy this guide on how to get Frostwalker in Minecraft. A loom is a new type of crafting table that allows you to take a banner, a dye and a banner pattern and weave them together to create amazing new banners. It takes your banners and assorted dyes, allowing you to select patterns to create unique and beautiful flags.Īlongside the loom, you will also need a small sheep farm if you want to save on dye. When creating a custom banner, you need to use a loom. You can see how to create all the types of Minecraft pride flags and be ready for Minecraft pride month in June. So I have created a simple process below to help you create pride banners and proudly show your gender and sexuality! However, creating a custom banner pattern can be difficult if you do not have an easy step-by-step to follow. The only thing that limits your ability to build is your creativity, and for members of the LGBTQIA+ community, this includes creating pride flags. In Minecraft, one of the greatest things about it is the ability to create anything you want within the game. ![]() PLEASE READ THE FULL DISCLOSURE FOR MORE INFO.įeatured image: I have placed all the primary pride flags after using the loom to create them. ![]() “I” IN THIS CASE MEANS THE OWNER OF GAMEDAFT.COM. inventory tool repair to the grindstone, banner modification to the loom. THIS POST MAY CONTAIN AFFILIATE LINKS, MEANING, AT NO ADDITIONAL COST TO YOU, I EARN FROM QUALIFYING PURCHASES. How2MC 64.1K subscribers Subscribe 66K views 3 years ago How To Banner How To Make A Fox Banner in Minecraft Learn how to craft a fox banner in Minecraft 1.16 I show off the crafting. Since the beginning of Minecrafts development, there have been a number of. DISCLOSURE: AS AN AMAZON ASSOCIATE I EARN FROM QUALIFYING PURCHASES. ![]() ![]() ![]() ![]() Simple right!, but by default, Qlab doesn’t see its own internal timecode, and unlike Veźer with OSCquery, Qlab needs you to add an extra little #v# at the end of the OSC address otherwise it will send the wrong values to the madmapper sliders.Īdditionally, most theatrical spaces love Qlab these days, so making a show file that they would understand is a lot easier than explain the intricacies of LED pixel mapping and custom OpenFrameworks camera apps (by Char Stiles). What I needed was on the second (at timecode) OSC fades. At first, I explored Veźer, and while I feel pretty confident that Veźer would have worked, a bit of its UI felt clunky for what I needed. The beginning would trigger a preshow look that would loop for as long as it took to seat the entire audience, and then would fade into the main show with more complicated changes and timings. I was building out slowdanger’s – empathy Machine show and needed a way to automate various visual changes over the 1hr+ performance. I’ll add more to this page if I make them. I'll have to check that out as well.I put two quick tutorials together for anyone interested. Thank you, also, to Margaret for the reference to a windows based cue system. The newest version evidently supports DMX cues as well, but haven't tried that. I don't use QLAB for video cues, mainly because we don't have the capacity for video in our space. This takes some time and practice to set up, but can make a difference when trying to create an immersive environment. We map each input channel to a different speaker using the Main L/R and Auxiliary outputs. We use the Pro version in productions as it supports multi-channel output through USB so we can use directed sound to practical speakers and various locations around the house. It takes about 2 minutes to close one show and open a saved one. This allows us to design multiple shows at the same time. After this, the show can be saved and shared using the "Bundle Workspace" command. We set up and design the cues on the free version, and this is generally sufficient for most productions. (That means that after 100 days of rental, you own it.) I rent the Pro version for tech week, and a few days before. And, I use my own systems for it and lighting anyway.Īs others have posted, the Pro version has a rent to own option, with the latest version at $4 per day. As a Mac user already, it makes sense for me to use it. Was introduced to QLAB while in the Master of Theatre Studies program as Southern Oregon University. I also liked that I could localize other sound effects: the clock tower upstage left street noise stage right the burglar walking around in the downstairs (orchestra pit house left) then climbing the stairs to the attic area, and being heard outside the Annex door (upstage right). So my actors could confidently cue off of specific sounds or lights for their reactions or lines. The beauty of using QLab for the sequence meant that it was exactly the same each time, whether in rehearsal or performance. And the entire bombing raid was triggered by one push of the space bar. If I remember correctly, the entire effect had over 50 separate sound and light cues. Once she was hands on, it was a piece of cake. Then I explained QLab and she was a little more confident. When I initially described the effect to my student in the booth, and told her she'd be running all lights and sound for the effect, she literally started to have a panic attack at the thought of that responsibility. Then the bombers flew off behind and to the left. Bombs fell from up high, and exploded all around them, with explosive flashes of light perfectly timed to the sound. During the bombings on Amsterdam our audience heard the planes approach from behind and to the right. The interface also provided MIDI connection to our ETC Element lighting console, so QLab could send MSC (MIDI Show Control) triggers to the lighting. I used an audio interface to give me 7 distinctive sources of sound - rear of house left and right speakers, left and right speakers in our orchestra pit, left and right speakers behind the set, and our main center cluster. Just an example of what it can do: We did Diary of Anne Frank and I used QLab to control all sound and lights. Their current plan is renting for 110 days equals buying a license. If you search for "QLab After Dark" you'll find a series of 14 video tutorials that touch on a lot of the capabilities of this software. Current cost is $4.00/day, and it accrues towards me owning a copy. ![]() I've rented the audio version for my last three production. ![]() If you try something with a cue that is not allowed in the free version, the software will flag the cue to let you know. It is worthwhile to download it, and experiment. The free version is very capable for basic stereo sound cues and basic video to one external monitor/projector. ![]() ![]() In this workaround, we’re going to use the macOS High Sierra Patcher app from the. I’ve found a new workaround, and in this tutorial, I’ll show you how to download the complete “Install macOS High Sierra.app” file from Apple server using the “macOS High Sierra Patcher” app instead of via the Mac App Store. Additionally, it does not allow me to create a macOS High Sierra USB installer drive for use on multiple computers. The tiny 19 MB incomplete installer requires an internet connection during usage to download the rest of the High Sierra update files. Attempting to download macOS High Sierra from the Mac App Store I found that a small 19 MB version of the “Install macOS High Sierra.app” file downloads to the “Applications” folder, rather than the complete 5.2 GB installer file. I began to figure out what was going on and found out the following. The progress bar did not move at all, or moved very slowly. The Mac rebooted, and it seemed that everything was going well, but it was not. ![]() But then I was facing multiple issues trying to update macOS from Mountain Lion to High Sierra via the Mac App Store.Īfter downloading a copy of macOS High Sierra from the Mac App Store, I started installing the update. I successfully installed the macOS Mountain Lion (when using the NetBoot it automatically selects the version of macOS with which the iMac was shipped with). ![]() I thought that it would be easy to do but I was mistaken. ![]() Recently my sister asked me to reinstall the macOS High Sierra on her iMac because it stopped working correctly. ![]() ![]() Later, PopCap Shanghai teamed up with Tencent Games to make their own take on Plants vs. Zombies: Great Wall Edition as a more local approach towards Chinese players on Plants vs. In response to this, they made Plants vs. PopCap Shanghai thought Plants Gone Wild was more successful because it was much more local to Chinese audiences compared to Social Edition. Zombies Online (not to be confused with the official game with the same name), also known as Plants Gone Wild in English versions of the game. Zombies: Social Edition failed to compete with a similar ripoff game called Plants vs. ![]() On August 11th, 2018, players were no longer able to log into the game and the entire website as well as the server were removed completely. ![]() These buildings and features had different activities that can resemble one of the three modes as well as rewards for them. It contained buildings that the player could unlock and a menu with many buttons, each led to a feature or a mode of the game. After a few levels in Normal Mode or Adventure Mode, the player would be lead into the town. Generally, the game had three modes: Normal Mode where the player defended their house from zombies around many worlds with plants in the original tower defense style an Adventure mode which had a gameplay that was similar to the popular mobile TCG "I AM MT", in which the player formed their own plants troop to battle against AI, as many as seven plant units which included one from the player's friend could be sent into battle and a Map mode where the player sent off one of their decks of plants in Adventure Mode into an empty or another user's mining location to conquer it for harvesting for rewards after. However, unlike it, it was a PC game with an online component with special gameplay elements of its own. Zombies Online was nearly identical to Plants vs. In terms of art style and gameplay features, Plants vs. Zombies Online, one had to create a QQ account. Zombies Online ( 植物大战僵尸Online pinyin: zhíwù dàzhàn jiāngshī Online), abbreviated as PvZO or PvZ Online, was a Chinese MMO SNS Tower defense game with simulation and RPG elements, released by PopCap Games and Tencent Games. ![]() ![]() ![]() And the AT-ST character in the trailer has left plenty of fan-generated questions to be considered until the game’s release. The primary Kingdom Hearts 4 plot may be altered, but the location (similar to the one in Endor). While it looks a lot like Shibuya, this city is known as Quadratum, a name we. The game has been revealed as part of the Kingdom Hearts ’. One of the biggest surprises in the Kingdom Hearts 4 reveal trailer might be the realistic world Sora wakes up in. The design could be inspired by the foot of AT-ST. Ap8:14 am ET Square Enix has just announced Kingdom Hearts 4, a new chapter in the long-standing action RPG series. With new skills which could allow him to travel to undiscovered realms, such as Endor of Star Wars.Ī large metal foot could be seen in the time frame of 4.42 on the film’s upper right corner. Since Sora is no longer Donald and Goofy The fans believe the programmers have chosen to provide him. The gorgeous green woodlands do not match the Quadratum region in Kingdom Hearts 4. With some speculating that it’s somehow linked to the events in Star Wars. Many theories have been proposed about the storyline that is Kingdom Hearts 4. ![]() Before that, the trailer offers glimpses of the forest. Sora is confronted by a massive Heartless There. This is the Afterlife for Sora A new planet named Quadratum. To be honest I’m hopeful that Kingdom Hearts 4 doesn’t come out on PS5 or Xbox Series X|S. We’ve not yet seen a full-on Kingdom Hearts mainstream game on the following system generations. It came out at the close of the life span of each console.ĭespite the game’s compatibility with backward. This was a few months before when the PS5 or Xbox Series X. It was released following the PS4 as well as Xbox One launches. However, Nana Gadd, director of Walt Disney Games, shared, "This glimpse into Sora’s next adventure is just the beginning – we can't wait to show more when the time is right.It’s noteworthy to note that Kingdom Hearts 3 came out a few days following.There is no release date for Kingdom Hearts 4 yet.This is not only the first glimpse at a brand-new mobile game called Kingdom Hearts – Missing Link, but it looks like it will receive a closed beta test later this year.The mobile game Kingdom Hearts: Dark Road has been delayed until August 2022.There was a press release where Square Enix shared, "Fans will be excited to see the return of Sora’s well-known companions, Donald and Goofy, in addition to the first appearance of Strelitzia, a mysterious new character who appears before Sora in this strange new setting.".This is an extensive city and more realistic than anything that the Kingdom Hearts series has seen before.They are fighting in a boss battle against the enemy across a location Square Enix is calling Quadratum.You're able to see an older Sora teaming up with Strelitzia from Kingdom Hearts Union X.This trailer has a bit of a darker and more serious tone than previous clips in the series. ![]()
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